Localized Surface Plasmon Resonance Dependence on Misaligned Truncated Ag Nanoprism Dimer.

Misaligned edge-to-edge dimers are the common products during the preparation of Ag nanoprism dimers using self-assembly method. However, in the self-assembly method, Ag nanoprisms are easily truncated because they are easy to oxidize in an acidic environment. In this work, modeling a truncated Ag nanoprism on a misaligned edge-to-edge dimer provides a better understanding of the effects of the truncation and misalignment on localized surface plasmon resonance (LSPR) of the dimer. The resonant wavelength and intensity of the dimer are flexibly modulated by changing the misalignment length of the dimer. As the misalignment length increases, a stronger peak at the shorter wavelength and a weaker one at the longer wavelength are observed. The resonant wavelengths and intensities of the two peaks are also flexibly tuned by adjusting the truncated length of the Ag nanoprism in the dimer. The results are numerically demonstrated based on the finite element method (FEM) and show promising potential for nanoswitch, multi-channel tunable biosensor and other nanodevice applications.