Electrocatalytic Mn

Metal oxide nanomaterials tailored at the nanoscale are opening new avenues for advanced electroanalytical sensing devices with enhanced properties, including improved electrocatalytic activity. In this work, a novel Mn2Mo3O8/MnO-MWCNT nanocomposite was employed to modify a screen-printed carbon electrode, enabling the fabrication of an amperometric sensor for H2O2 operating at relatively low applied potential due to the catalytic activity of the nanocomposite. Further functionalization of this nanostructured surface with glucose oxidase allowed the construction of an electrochemical glucose biosensor, where the Mn2Mo3O8/MnO-MWCNT material acted as an efficient electrocatalyst for hydrogen peroxide detection. The H2O2 sensor exhibited a linear response from 0.06 mM to 3.00 mM, with a sensitivity of (2.22 ± 0.02) µA mM-1 and a detection limit of 22 µM. The glucose biosensor showed a linear response in the range from 0.10 mM to 18.9 mM glucose, with a sensitivity of (0.345 ± 0.005) µA mM-1, and a detection limit of 29 µM. The biosensor displayed excellent selectivity and high stability and was successfully applied to the determination of glucose in lactose-free skimmed milk.