Tricarboxylic-Ligand-Decorated Lanthanoid-Inserted Heteropolyoxometalates Built by Mixed-Heteroatom-Directing Polyoxotungstate Units: Syntheses, Structures, and Electrochemical Sensing for 17β-Estradiol.

有机–无机杂化金属氧化物簇因结构丰富、性能突出而备受关注。本文报道了一类由混合杂原子（SbIII、PIII）导向的镧系（Ln）掺杂杂多钨酸盐（Ln-HPOTs）[(CH3)2NH2]2Na7H3[Ln4(HPIII)W8(H2O)12(H2ptca)2O28][SbIIIW9O33]2·27H2O（Ln=Ce3+、La3+、Pr3+...